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EVACUATE THE
SPILL AREA:
Before people leave, be sure that their shoes, clothing, and other
articles have not been splashed with mercury. Secure the scene
(use barrier tape if necessary) and restrict admission to only
those persons necessary to clean up the spill. Children and pets
should be kept clear of the spill area.
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LOWER the TEMPERATURE by turning down the thermostat.
The cooler the temperature, the less mercury vapors that will be
released into the air. [For example, a temperature increase from
64.4°F to 78.8°F will double mercury’s vapor pressure.] Remember
that mercury vapors are odorless and colorless.
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TURN
OFF VENTILATING
OR AIR
CONDITIONING SYSTEMS that could circulate air from the spill
area to other parts of the building
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CLOSE INTERIOR
DOORS leading to other inside areas and open exterior doors
and windows.
CAUTION: Mercury vapors are readily
absorbed through the lungs into the bloodstream and are,
therefore, particularly hazardous. In extreme situations, even
very small amounts of metallic mercury (several drops) may raise
air concentrations to levels that may be harmful to human health.
Mercury vapors are also heavier than air and may linger in higher
concentrations close to the floor. Children that crawl or play in
these areas are at highest risk to exposure.
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DETERMINE
IF THE SPILL MUST BE REPORTED under federal, state, or local
reporting requirements. Note: It is recommended
that any mercury spill equal to or greater than 1 pound (more than
two tablespoons) impacting the environment, i.e., groundwater and
surface water, or that threatens public health, be reported
immediately.
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CONTAIN THE
SPILL: Surround or block off the mercury to keep it from
spreading onto sloped or porous surfaces. Divert all mercury away
from floor drains, cracks, or crevices that may impact
groundwater, surface water, and soils.
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VENTILATE
THE ROOM to the outdoors. (Use fans to force air circulation
for a minimum of one hour after clean up). In an office building,
increase the air exchange rate for one day. The danger
of mercury exposure is greatest in small, confined, poorly
ventilated areas. Avoid breathing any dust, vapors, mist,
or gas. Avoid contact with eyes, skin, and clothing.
Never use a
household vacuum cleaner or shop vac to clean up mercury! (These
devices are not adequately filtered and will spread mercury
vapors.)
Special mercury vacuums
are commercially available for larger spills but require advanced
training to operate properly. When necessary, they may be obtained
by contacting local universities or environmental health
departments or provided for a fee by professional spill
remediation contractors.
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ASSEMBLE
CLEAN UP SUPPLIES or obtain a mercury spill kit. Mercury spill
kits are commercially available and convenient, but not absolutely
necessary to clean up a small mercury spill.
The
following are some common household articles that could be used to
construct an in-home mercury cleanup kit:
-
eye dropper
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goggles
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paper towel
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plastic container with lid
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plastic sheeting
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powdered zinc *2
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rubber squeegee
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tape; wide, duct, or masking
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tray or box |
|
|
*1-
visualizes mercury by turning from yellow to brown and forms
mercuric sulfide. Dusting the area with this powder also
reduces mercury vapors. *2-
amalgamates (bonds with) mercury. Note: Used
items are to be double-bagged and disposed of in accordance
with state and local requirements.
|
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DRESS
APPROPRIATELY: Remove all jewelry from hands and wrists so the
mercury does not combine (amalgamate) with the precious metals.
Change into old clothes and shoes that can be safely discarded
should they happen to become contaminated. Put on rubber gloves
and goggles or safety glasses.
Never use a broom on a mercury
spill because it will only scatter the mercury droplets, making
them harder to find and pick up.
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PICK UP ALL VISIBLE
MERCURY DROPLETS: Inspect the spill zone with a bright light
to help illuminate any hidden droplets. Clean up any metallic
beads of mercury by using a plastic squeegee or index card and
plastic dust pan. With the index or plastic card, sweep the
mercury toward the center of the spilled area away from any
carpet, fabric, or porous surfaces. Carefully combine and
consolidate the mercury droplets. Next, slide droplets onto a
sheet of rigid paper like an index card.
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NEXT, GENTLY TRANSFER MERCURY INTO AN UNBREAKABLE PLASTIC
CONTAINER like a 35mm film canister with a locking or air
tight lid (avoid using
glass). If necessary, suction off the droplets using an eye
dropper or syringe. Adhesive tape strips may also be used to clean
up any tiny remaining mercury droplets. Place the plastic
container inside a second plastic container to provide additional
containment protection. Tighten each lid securely so that liquid
and vapors will be contained.
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PLACE THE MERCURY
WASTE CONTAINER(S) INTO A ZIP-TOP PLASTIC BAG: This should
ensure that in the event of any leakage, all mercury will be
safely
contained within the packaging. Label the package “Elemental
Mercury Waste, [Hazardous],” and store in a secure place away from
children. Contact your local health department or the Michigan
Department of Environmental Quality (DEQ) to obtain a list of
disposal locations.
Never pour
liquid mercury or mercury compounds down the drain. Since mercury
is heavier than water, it will accumulate in the S-trap of your
drain and may continue to emit harmful vapors.
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REMOVE and
DISPOSE OF CONTAMINATED CARPETING or other articles that have
directly contacted mercury. It may be necessary to remove
contaminated carpet from the room where the spill incident
occurred. Double or triple wrap these remnants in plastic trash
bags and contact your local waste department for proper disposal.
(Do not expose to
heat or incinerate.)
Special precautions should be taken
if mercury was spilled in a high traffic area or a confined area
where children or infants play. Young children playing on the
floor are particularly at risk to mercury’s effects on the central
nervous system. If this sounds like your situation, discuss the
incident with your family doctor to determine whether additional
mercury testing should be conducted for your family. In extreme
instances, additional measures may be recommended.
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SPRINKLE
FINE POWDER SULFUR OR ZINC ON THE SPILL SITE to bind any
remaining mercury. This may be supplied in mercury spill kits as
mercury vapor absorbent or purchased separately from garden supply
stores or chemical supply houses. Apply over hard to reach areas
such as cracks and crevices to minimize the release of mercury
vapors. In instances where furniture has been exposed to mercury,
wash fabric thoroughly and allow all items to air out completely.
Mercury may lodge in porous areas like carpet backing or cracks
and crevices.
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CHECK CAREFULLY
FOR MISSED MERCURY: To aid in detection, a high intensity lamp
may be used to better illuminate the spill area. The presence of
scattered mercury droplets may also be detected by a sodium
sulfide solution, which can be obtained from most
chemical
supply houses. This solution may also be sprayed on an affected
person (but not the
eyes, mucous membranes, or the mouth). Any mercury present will
show up as dark, reddish brown stains.
Residual mercury may then be uplifted using a variety of
techniques including vinegar wash followed by hydrogen peroxide.
To combat any hydrogen sulfide odors generated from mixing the two
chemicals, an alternate method would be to wipe the area with a
vinegar-soaked swab, followed by a peroxide wipe.
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SET ASIDE EVERYTHING
YOU THINK MIGHT BE CONTAMINATED WITH MERCURY: Package
materials securely and label as “Elemental Mercury: Hazardous
Waste.” Specific labeling and disposal requirements may differ
depending on whether the spill occurred at a household or at a
‘regulated business.’ See: DEQ Waste Management Division (WMD)
Internet site or contact WMD district staff for details. Then
contact your local health department or DEQ to obtain a list of
possible disposal locations.
Never place
heavily mercury-laden fabrics in a washing machine.
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DO
NOT PLACE MERCURY-CONTAMINATED SUBSTANCES IN THE TRASH
unless otherwise instructed to do so by proper authorities. This
is especially important if your trash goes to an incinerator
(municipal waste combustor). Contact the DEQ, your local county
health department, or household hazardous waste collection program
for proper disposa1 suggestions.
Mercury
Recycling (where to take spilled mercury)
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MONITOR SPILL
ZONE FOR MERCURY VAPORS:
Even if the impacted area appears
clean, there may still be hidden residual quantities of mercury
present that emit vapors. For larger-sized spills, it may be
necessary to monitor (test) mercury vapor levels in the immediate
area. If mercury is detected, re-clean the impacted area using
previously mentioned procedures and repeat testing until levels
fall to within safe parameters (.3ug/m3;
recommended in-home cleanup guideline). Note: This recommendation
would not
normally be necessary for incidents involving the breakage of
typical (standard-size) mercury fever thermometers.
For
larger spills in sensitive areas (bedrooms or poorly ventilated,
confined areas), a direct reading mercury vapor meter may be used
to detect the presence of mercury. In extreme (human
exposure) situations, mercury monitoring (testing) of blood plasma
or urine might also be deemed necessary. Consult your doctor,
local county environmental health department, or the Michigan
Department of Community Health (800-MI-Toxic) for further guidance
and assistance.
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WASH HUMANS AND
ANIMALS EXPOSED TO MERCURY using an alkaline soap (i.e., Lava
soap) and a paste of water and flowers of sulfur. Flowers of
sulfur can be found in most garden supply shops and will turn the
mercury into an insoluble sulfide. Afterwards, the remaining
residue should be thoroughly rinsed. All wash water containing
mercury should be collected and kept out of the sanitary sewer
system.
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CONTINUE
VENTILATION to completely air out the room or spill zone with
outside air for a minimum of two days, preferably
longer.
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REPLACE BROKEN
DEVICE WITH A ‘MERCURY-FREE’Alternative: For a
detailed listing of mercury-containing devices and alternatives
see:
-
INVENTORY
ALL REMAINING MERCURY-CONTAINING DEVICES AND REPLACE THEM WITH
MERCURY FREE ALTERNATIVES: The best way to address a mercury
spill is to prevent it from ever happening in the first place. For
additional pollution prevention ideas and assistance contact the
DEQ’s Environmental Assistance Center at
800-662-9278.